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Full text of "Treatise On Applied Analytical Chemistry(Vol-1)"

FORMALDEHYDE

67

sulphate.    As  impurities  it  may contain  especially copper,  zinc,  man-
ganese, magnesium, arsenic, ferric salts and free sulphuric acid.

1.  Copper, Zinc.—3 grams are dissolved in water, boiled with nitric
acid, and precipitated with excess of ammonia ;  after filtration, the nitrate
is tested for copper and zinc by the ordinary methods.

2.  Ferric Salts.—The sample is dissolved in recently boiled water,
acidified with a little hydrochloric acid and tested with ammonium thio-
cyanate.

3.  Free Sulphuric Acid.—The aqueous solution, prepared with boiled
water, should not redden blue litmus paper.

4.  Other Impurities.—3 grams are dissolved in water and oxidised
by boiling with nitric acid;   after precipitation with ammonia and filtra-
tion, the lime, magnesia, arsenic and any other impurities are sought in the
filtrate.

FORMALDEHYDE

CH20 = 30

This is sold in aqueous solution under the name Formal or Formalin
and is a colourless liquid with a peculiar, irritating odour, D = about 1-08 ;
it contains 35-40 grams of formaldehyde per 100 c.c. The commercial
product may be contaminated with formic and acetic acids, methyl alcohol,
acetone, chlorides, sulphates, copper and calcium; its value depends
essentially on the content of formaldehyde.

1.  Acidity.—Tested with litmus paper ;  an acidity corresponding with
a drop of N-alkali per I c.c. of the sample is allowable.

2.  Sulphuric Acid, Hydrochloric Acid, Metals.—These are detected
in the I : 5 solution in the usual way.

3.  Methyl Alcohol.—50 c.c. are treated with 100 c.c. of 10% ammonia,
with which the formaldehyde combines, forming hexamethylenetetramine ;
after a rest of 6 hours in a closed vessel, the greater part of the liquid is
distilled off.    The distillate is acidified with a slight excess of dilute sulphuric
acid and redistilled, the temperatures at which the first fractions distil
being observed:   in presence of methyl alcohol, these will come over at
about 66° and may be tested for methyJ alcohol (see Spirits :  Detection of
Denaturants).

By collecting 50 c.c. of distillate (after acidification) and determining
its specific gravity, the quantity of methyl alcohol present may be found
approximately from the table on p. 40.

4.  Acetone.—A few c.c. are treated with sodium hydroxide and iodine
solution :   in presence of acetone, iodoform is formed immediately in the
cold.

5.  Determination   of  the  Formaldehyde   (lodornetric  method  of
Fresenins and Grunhut).—25 c.c. are diluted with water to 500 c.c. and
5 c.c. of the solution (= 0-25 c.c. of substance) introduced into a bottle
of about 200 c.c. capacity fitted with a ground stopper ; 30 c.c. of N-sodium
hydroxide are then added rapidly from a graduated cylinder and, from a
burette and with shaking, 50 c.c. of N/5-iodine solution (the liquid shouldl. It often exhibits yellowish spots of ferric oxide orpanto with a little water and poured into 200 o.c.